My bubble evolution continued

 I hypothesis a long period of chemistry with no life, and only Boltzmann and the random, consistent energy flows in the pond.  Reversible reaction would tend to congregate, Otherwise the others wash away looking for another pond. We get chemical layering and we get nice balances of phosphorous and nitrogen.  Bubbles make reversible chemistry chanbers.

But we get layering, like skin. In an environment with a stable variety of short amino acids and  we get partition between those that sustain reversible reaction at the current energy flow down through the pond. An active reactant filter, a skin. Which actions are reversible? The ones that can do a symmetric switch across a nitrogen axis. That means all the nitrogen configuration mostly have a swap which neutralizes. A consistent surface tension can be maintained 

Nitrogen and Phosphorous will hang there is reversible quantities with phosphorous at the bottom. 

What happens to the odd ball nitrogen forms? They drift to the bottom and pack in. If exposed to sudden energy they cannot form complements and form tertiaries with phosphorous.  As such they consume the left overs sufficiently to set a barrier, a point under the skin layer where there is no matching with the skin. 

This is Boltzmann still, generating useless work from excess energy flow. The result are partitions among set of reversible reactions. There are no reaction to blow off steam,  it is hot and humid at the surface, the vents bubble at the bottom. There is a point where the two flows balance, a surface, and reversible reactants will converge. The collisions align movements, and there is a layer that minimizes collisions, a Markov spot. Nitrogen and Phosphorous will hang there is reversible quantities.  They will layer such that the rate of water and carbon passage vertical to the equal energy surface is constant. This minimizes collisions. maximizes reversal flow. 

The tertiary structure nearthe hot spouts have one extra degree of freedom than a flat surface pond.  They cause exchanging of surface aminos to force curvature ad we get colonies of chemical reactants small reversible built around each hot spot.   This is all Boltzmann distribution charge among a finite set of configurations in a consistent energy flow with a hard boundary. There is no other entropy maximizing choice except useless partitions.   Energy flow, Planck radiation and absorption, temperature and concentrations will find their balance because excess collisions result in kinetic movement along the equilirbiating axis. But introducing the tertiary axis means the center can deliver exothermic reactants by spherical tension. That forces the sin to shed more complex hydro carbons, carbons with tertiary form. That is water storage, that lengthens the life time of our chemical reactor.

Sex and seasonality

Our chemical reactant bubble chambers under go seasonality when the pond dries and the bubbles shrink to a ht mix of amino skin layer and the tertiaries phosporous and complex hydro carbons from exothermic. . We get pseudo proteins, asnd along with that we get chiral.  What happens when Boltzmann partitions chirility? We get a disrete torus, we get some small, finite pods of pseudo protein that collects all the ingredients for reproduction, in a circle about the hot spot. The wind can blow one of these pods over to another hot spot, and wait for the rains..

That is life, that is chemistry. It works because Boltzman is stuck, he cannot get the radiation he needs, he is stuck with too much energy flow and needs to get kinetic energy axes. Botzmann does random work where he can find it. In the end the only way to dissipate the energy is wind and clumps of dry pseudo proteins.

This balance could only be found at a certain latitude where the sequence of reactions can be maintained through the stages in the season. Like the chemist doing tow step reaction and has to leave the intermediate step a a cold temperature for a specific length of time. That matching point created reproducible life, it is the alternating generations concept, two phases for the right combination, and a path from one to the other.